Physician
Psychiatry
Dr. Robert J. Mulvey, MD
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Dr. Robert J. Mulvey works in the field of Psychiatry. He researched medicine at Tufts University School of Medicine. Tufts University School of Medicine has a rank of 49 in research and a 52 in primary care Doctor Robert J. Mulvey, MD is also a published physician. He has 91 publication published. The most recent publication is: After-effects of lithium-mediated alumination of 3-iodoanisole: isolation of molecular salt elimination and trapped-benzyne products.
Publications
- Single electron transfer (SET) activity of the dialkyl-amido sodium zincate [(TMEDA)·Na(μ-TMP)(μ-tBu)Zn(tBu)] towards TEMPO and chalcone.
- A monomeric three-coordinate magnesium bis(amide).
- Dichlorobis(dibenzylamino)bis(tetrahydrofuran)zirconium(IV) toluene hemisolvate.
- Trimagnesium-bridged trinuclear ferrocenophanes cocomplexed with solvated mononuclear alkali metal amide molecules.
- Hexameric Mg-O stacks with six THF-solvated sodium amide appendages: "super" variants of inverse crown ethers generated by cleavage of THF.
- Hydride encapsulation in s-block metal inverse crown chemistry.
- Alkoxide binding in inverse crown chemistry: rational synthesis of a series of composite alkali metal-magnesium-alkoxide-diisopropylamides.
- After-effects of lithium-mediated alumination of 3-iodoanisole: isolation of molecular salt elimination and trapped-benzyne products.
- Meta-metallation of N,N-dimethylaniline: Contrasting direct sodium-mediated zincation with indirect sodiation-dialkylzinc co-complexation.
- Neutral zinc, lower-order zincate and higher-order zincate derivatives of pyrrole: synthesis and structural characterisation of zinc complexes with one, two, three or ...
- "LiZn(TMP)3", a zincate or a turbo-lithium amide reagent? DOSY NMR spectroscopic evidence.
- Main group multiple C-H/N-H bond activation of a diamine and isolation of a molecular dilithium zincate hydride: experimental and DFT evidence for alkali metal-zinc sy...
- A record-breaking magnesium hydride molecular cluster: implications for hydrogen storage.
- Crossing organolithium compounds with organolithium compounds: molecular squares and a cage-encapsulating reaction.
- A μ4-oxide-containing a dimeric variant of a sodium dialkyl(amido)zincate reagent.
- Split personality of lithium chloride: recent salt effects in organometallic recipes.
- Molecular structures of THF-solvated alkali-metal 2,2,6,6-tetramethylpiperidides finally revealed: X-ray crystallographic, DFT, and NMR (including DOSY) spectroscopic ...
- Structurally powered synergic 2,2,6,6-tetramethylpiperidine bimetallics: new reflections through lithium-mediated ortho aluminations.
- Sodium congener of the classical lithium methylchromate dimer: synthetic, X-ray crystallographic, and magnetic studies of Me8Cr2[Na(OEt2)]4.
- Exploiting Ï/Ï coordination isomerism to prepare homologous organoalkali metal (Li, Na, K) monomers with identical ligand sets.
- Confinement of halide ions within homologous inverse coordination hosts; modification of halide-ion selectivity.
- Structurally engineered deprotonation/alumination of THF and THTP with retention of their cycloanionic structures.
- N-Heterocyclic carbene stabilized adducts of alkyl magnesium amide, bisalkyl magnesium and Grignard reagents: trapping oligomeric organo s-block fragments with NHCs.
- Synergic transformation of an ethylenediamine to a lithium 1,3-diaza-2-zincacyclopentene via an alkyllithium/bis(alkyl)zinc mixture.
- Sodium-mediated magnesiation of thiophene and tetrahydrothiophene: structural contrasts with furan and tetrahydrofuran.
- Cleave and capture chemistry illustrated through bimetallic-induced fragmentation of tetrahydrofuran.
- Structural basis for regioisomerization in the alkali-metal-mediated zincation (AMMZn) of trifluoromethyl benzene by isolation of kinetic and thermodynamic intermediates.
- Lithium and aluminium carbamato derivatives of the utility amide 2,2,6,6-tetramethylpiperidide.
- Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines.
- Diisopropylamide and TMP turbo-Grignard reagents: a structural rationale for their contrasting reactivities.
- Structurally stimulated deprotonation/alumination of the TMP anion.
- Structural elaboration of the surprising ortho-zincation of benzyl methyl ether.
- cis-2,6-Dimethylpiperidide: a structural mimic for TMP (2,2,6,6-tetramethylpiperidide) or DA (diisopropylamide)?
- Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations.
- Synergic sedation of sensitive anions: alkali-mediated zincation of cyclic ethers and ethene.
- Synergic synthesis of benzannulated zincabicyclic complexes, alpha-zincated N ylides, through sodium-TMEDA-mediated zincation of a haloarene.
- Alkali-metal-mediated manganation(II) of naphthalenes: constructing metalla-anthracene and metalla-phenanthrene structures.
- Structural tracking of the potassium-mediated magnesiation of anisole.
- Structurally defined potassium-mediated zincation of pyridine and 4-R-substituted pyridines (R = Et, iPr, tBu, Ph, and Me2N) by using dialkyl-TMP-zincate bases.
- Structural variations within group 1 (Li-Cs)+ (2,2,6,6-tetramethyl-1-piperidinyloxy)- complexes made via metallic reduction of the nitroxyl radical.
- Avant-garde metalating agents: structural basis of alkali-metal-mediated metalation.
- Synthetic and structural insights into the zincation of toluene: direct synergic ring metallation versus indirect nonsynergic lateral metallation.
- Closer insight into the reactivity of TMP-dialkyl zincates in directed ortho-zincation of anisole: experimental evidence of amido basicity and structural elucidation o...
- Direct C-H metalation with chromium(II) and iron(II): transition-metal host/benzenediide guest magnetic inverse-crown complexes.
- Structural and magnetic insights into the trinuclear ferrocenophane and unexpected hydrido inverse crown products of alkali-metal-mediated manganation(II) of ferrocene.
- A mechanistic study of the C-P bond cleavage reaction of 1,2-(PH2)2-C6H4 with nBuLi/Sb(NMe2)3.
- Structural complexity of the magnesiation of furan: an octadecanuclear product with a subporphyrin-like Mg3(2,5-fur-di-yl)3 substructure.
- Unmasking representative structures of TMP-active Hauser and turbo-Hauser bases.
- A structural and computational study of synthetically important alkali-metal/tetramethylpiperidide (TMP) amine solvates.
- Tuning the basicity of synergic bimetallic reagents: switching the regioselectivity of the direct dimetalation of toluene from 2,5- to 3,5-positions.
- Structurally-defined potassium-mediated regioselective zincation of amino- and alkoxy-substituted pyridines.
- Synthesis and structure of the Li13 cage [[[O-P(mu-NtBu)]2Li2]3(LiCl)6Li(Cl/OnBu)0.5(thf)7], containing a [O-P(mu-NtBu)]2(2-) dianion.
- Manganese(II)-lithium and -sodium inverse crown ether (ICE) complexes.
- Synthesis and characterisation of new bimetallic alkali metal-magnesium mixed diisopropylamide-acetylides: structural variations in bimetallic lithium- and sodium-hete...
- Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate.
- Structurally defined reactions of sodium TMP-zincate with nitrile compounds: synthesis of a salt-like sodium sodiumdizincate and other unexpected ion-pair products.
- Isolation and structural elucidation of a key aluminoaromatic intermediate and evidence for dismutation phenomena in TMP-alumination chemistry.
- Alkali-metal-mediated manganationII of functionalized arenes and applications of ortho-manganated products in Pd-catalyzed cross-coupling reactions with iodobenzene.
- Lewis base stabilized lithium TMP-aluminates: an unexpected fragmentation and capture reaction involving cyclic ether 1,4-dioxane.
- Structurally-defined direct C-magnesiation and C-zincation of N-heterocyclic aromatic compounds using alkali-metal-mediated metallation.
- Structural variations in bimetallic sodium-magnesium and sodium-zinc ketimides, and a sodium-zinc alkide-alkoxide-amide: connections to ring-stacking, ring-laddering, ...
- Sodium-mediated manganation: direct mono- and dimanganation of benzene and synthesis of a transition-metal inverse-crown complex.
- Organometallic polymers assembled from cation-pi interactions: use of ferrocene as a ditopic linker within the homologous series [{(Me3Si)2NM}2.(Cp2Fe)]infinity (M=Na,...
- Deprotonative metalation using ate compounds: synergy, synthesis, and structure building.
- Dizincation and dimagnesiation of benzene using alkali-metal-mediated metallation.
- Alkali-metal-mediated manganation: a method for directly attaching manganese(II) centers to aromatic frameworks.
- New reactivity and structural insights of alkali-metal-mediated alumination in directed ortho-alumination of a tertiary aromatic amide.
- Alkali-metal-mediated zincation of polycyclic aromatic hydrocarbons: synthesis and structures of mono- and dizincated naphthalenes.
- A polymeric solvent-free variant of a hydridomagnesium inverse crown.
- Alkali-metal-mediated zincation of anisole: synthesis and structures of three instructive ortho-zincated complexes.
- Directed meta-metalation using alkali-metal-mediated zincation.
- Post-metalation structural insights into the use of alkali-metal-mediated zincation for directed ortho-metalation of a tertiary aromatic amide.
- Pre-metalation structural insights into the use of alkali-metal-mediated zincation for directed ortho-metalation of a tertiary aromatic amide.
- Building an extended inverse crown motif via alkali-metal-mediated alpha-magnesiation of furan.
- Trapping, stabilization, and characterization of an enolate anion of a 1,6-adduct of benzophenone chelated by a sodium alkylamidozincate cation.
- Alkali-metal-mediated zincation of ferrocene: synthesis, structure, and reactivity of a lithium tmp/zincate reagent.
- A mixed iron(III)/lithium alkoxide.
- Sodium dialkyl-amidozincates: alkyl or amido bases? An experimental and theoretical case study.
- Selective meta-deprotonation of toluene by using alkali-metal-mediated magnesiation.
- Synthesis and characterisation of a series of alkylmagnesium amide and related oxygen-contaminated "alkoxy" compounds.
- Stoichiometrically-controlled reactivity and supramolecular storage of butylmagnesiate anions.
- Crystallographic characterisation of binary alkali metal alkoxide-magnesium bis(alkyl) mixtures: differential binding of Na+ and K+ to a common dinuclear diorganomagne...
- Isolation and characterisation of the mixed-metal alkyl amide [(TMEDA)Na(mu-Bu)(mu-TMP)Mg(TMP)], an unexpected chelate-trapped intermediate in the formation of inverse...
- Synergic monodeprotonation of bis(benzene)chromium by using mixed alkali metal-magnesium amide bases and structural characterization of the heterotrimetallic products.
- A homologous series of regioselectively tetradeprotonated group 8 metallocenes: new inverse crown ring compounds synthesized via a mixed sodium-magnesium tris(diisopro...
- Ketone deprotonation mediated by mono- and heterobimetallic alkali and alkaline earth metal amide bases: structural characterization of potassium, calcium, and mixed p...
- Synthesis and crystal structure of [[nBuMg(mu-TMP)]2] and of a homometallic inverse crown in tetranuclear [[nBuMg2[mu-N(H)Dipp]2(mu 3-OnBu]2].
- A new Na/Mg inverse crown ether.
- Synthesis of the mixed lithium-potassium-(bis)magnesium N-metallated/N, C-dimetallated amide [Li2K2Mg4[But(Me3Si)N]4[But[Me2(H2C)Si]N]4]: an inverse crown molecule wit...
- Potassium-zinc induced synergic enhancement of the basicity of hexamethyldisilazide (HMDS) towards methylbenzene molecules.
Schools
Tufts University
Boston City Hospital Ma
Metropolitan State Hospital Ma
New England Med Center Ma
Va Hospital Ny
Doctors Specialties
- Psychiatry
Accepted Insurances
Education
-
Tufts Medical Center -
NYU School of Medicine -
Boston University Medical Center -
Tufts University School of Medicine
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